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The Collaborative International Dictionary of English v.0.48:

Pulvil \Pul"vil\, n. [It. polviglio, fr. L. pulvis, pulveris, dust, powder: cf. Sp. polvillo.] A sweet-scented powder; pulvillio. [Written also pulville.] [Obs.] --Gay. [1913 Webster]
The Collaborative International Dictionary of English v.0.48:

Pulvil \Pul"vil\, v. t. To apply pulvil to. [Obs.] --Congreve. [1913 Webster] Pulvillio