The Collaborative International Dictionary of English v.0.48:

Polyhedral \Pol`y*he"dral\, Polyhedrical \Pol`y*hed"ric*al\, a.
   [See Polyhedron.] (Geom.)
   Having many sides, as a solid body.
   [1913 Webster]

   Polyhedral angle, an angle bounded by three or more plane
      angles having a common vertex.
      [1913 Webster]

WordNet (r) 3.0 (2006):

polyhedral
    adj 1: of or relating to or resembling a polyhedron