The Collaborative International Dictionary of English v.0.48:

Predestine \Pre*des"tine\, v. t. [imp. & p. p. Predestined; p.
   pr. & vb. n. Predestining.] [Cf. F. pr['e]destiner. See
   Predestinate.]
   To decree beforehand; to foreordain; to predestinate.
   --Young.
   [1913 Webster]

WordNet (r) 3.0 (2006):

predestine
    v 1: decree or determine beforehand
    2: foreordain by divine will or decree [syn: predestine,
       predestinate, foreordain]
    3: foreordain or determine beforehand [syn: predestine,
       foreordain, preordain]