The Collaborative International Dictionary of English v.0.48:
Empeople \Em*peo"ple\ ([e^]m*p[=e]"p'l), v. t.
To form into a people or community; to inhabit; to people.
[Obs.]
[1913 Webster]
We now know 't is very well empeopled. --Sir T.
Browne.
[1913 Webster]